Experimental Investigation and Modelling of Asphaltene Precipitation during Gas Injection

Document Type : Research Paper

Authors

1 Faculty of Chemical and Petroleum Engineering, Razi University, Kermanshah, Iran

2 Department of Petroleum Engineering, Petroleum University of Technology (PUT), Ahvaz, Iran

Abstract

Due to the limited crude oil resources, the role of enhanced oil recovery (EOR) techniques in the production of the oil that has not been extracted during the primary and secondary oil production techniques is crucial. Gas injection is known as an important EOR technology, but one of the main concerns during gas injection is asphaltene precipitation and deposition within reservoir formation. In this study, the effect of temperature (ranges 376-416 K) and concentration of injected gas (N2 (10, 20 and 40, mole percent) and first separator gas (20, 40 and 60, mole percent)) on the onset pressures and amount of asphaltene precipitation in one of the Iranian oil reservoirs were investigated. Two series of experiments were accomplished on live oil by gravimetric method; first: injection of different concentrationsof nitrogen and first separator gas at reservoir temperature and under different pressures (3000-8000 psia) and second: natural depletion at different temperatures. Besides, the experimental data of asphaltene precipitation due to N2, first separator gas, and also CO2 injection were compared together. Finally, the experimental data were modeled with a solid model. The results indicate that the amount of asphaltene precipitation due to N2 injection (0.1-0.2 wt %) is lower than the first separator gas and CO2 injection at the same concentration. Experiments show that in the range of experimental temperatures the asphaltene precipitation changes up to 0.06 wt %. For pressures below the bubble pressure (~ 4700 psi), precipitation changes directly with temperature, and indirect relation is observed for pressures above the bubble point pressure.

Keywords


[1] Wang P, Zhao F, Hou J, Lu G, Zhang M, Wang Z. Comparative analysis of CO2, N2, and gas mixture injection on asphaltene deposition pressure in reservoir conditions. Energies. 2018 Sep;11(9):2483.
[2] Alagorni AH, Yaacob ZB, Nour AH. An overview of oil production stages: enhanced oil recovery techniques and nitrogen injection. International Journal of Environmental Science and Development. 2015 Sep 1;6(9):693-701.
[3] Piccaglia R, Marotti M. Characterization of some Italian types of wild fennel (Foeniculum vulgare Mill.). Journal of Agricultural and Food Chemistry. 2001 Jan 15;49(1):239-44.
[4] Zekri AY, Shedid SA, Almehaideb RA. An experimental investigation of interactions between supercritical CO2, aspheltenic crude oil, and reservoir brine in carbonate cores. InInternational Symposium on Oilfield Chemistry 2007 Jan 1. Society of Petroleum Engineers.
[5] Subramanian S, Simon S, Sjöblom J. Asphaltene precipitation models: a review. Journal of Dispersion Science and Technology. 2016 Jul 2;37(7):1027-49.
[6] Arya A, Liang X, von Solms N, Kontogeorgis GM. Prediction of gas injection effect on asphaltene precipitation onset using the cubic and cubic-plus-association equations of state. Energy & Fuels. 2017 Mar 16;31(3):3313-28.
[7] Rastgoo A, Kharrat R. Investigation of asphaltene deposition and precipitation in production tubing. International Journal of Clean Coal and Energy. 2017 Jan 10;6(1):14-29.
[8] Hemmati-Sarapardeh A, Alipour-Yeganeh-Marand R, Naseri A, Safiabadi A, Gharagheizi F, Ilani-Kashkouli P, Mohammadi AH. Asphaltene precipitation due to natural depletion of reservoir: Determination using a SARA fraction based intelligent model. Fluid Phase Equilibria. 2013 Sep 25;354:177-84.
[9] Zendehboudi S, Ahmadi MA, Mohammadzadeh O, Bahadori A, Chatzis I. Thermodynamic investigation of asphaltene precipitation during primary oil production: laboratory and smart technique. Industrial & Engineering Chemistry Research. 2013 May 1;52(17):6009-31.
[10] Bouhadda Y, Bormann D, Sheu E, Bendedouch D, Krallafa A, Daaou M. Characterization of Algerian Hassi-Messaoud asphaltene structure using Raman spectrometry and X-ray diffraction. Fuel. 2007 Aug 1;86(12-13):1855-64.
[11] Neuhaus N, Nascimento PT, Moreira I, Scheer AP, Santos AF, Corazza ML. Thermodynamic analysis and modeling of brazilian crude oil and asphaltene systems: an experimental measurement and a pc-saft application. Brazilian Journal of Chemical Engineering. 2019 Mar;36(1):557-71.
[12] Mullins OC, Sabbah H, Eyssautier J, Pomerantz AE, Barré L, Andrews AB, Ruiz-Morales Y, Mostowfi F, McFarlane R, Goual L, Lepkowicz R. Advances in asphaltene science and the Yen–Mullins model. Energy & Fuels. 2012 Jul 19;26(7):3986-4003.
[13] Soleymanzadeh A, Yousefi M, Kord S, Mohammadzadeh O. A review on methods of determining onset of asphaltene precipitation. Journal of Petroleum Exploration and Production Technology. 2019 Jun 1;9(2):1375-96.
[14] Alhreez M, Wen D. Molecular structure characterization of asphaltene in the presence of inhibitors with nanoemulsions. RSC advances. 2019;9(34):19560-70.
[15] Santos D, Filho EB, Dourado RS, Amaral M, Filipakis S, Oliveira LM, Guimarães RC, Santos AF, Borges GR, Franceschi E, Dariva C. Study of asphaltene precipitation in crude oils at desalter conditions by near-infrared spectroscopy. Energy & Fuels. 2017 May 18;31(5):5031-6.
[16] Eshraghi SE, Kazemzadeh Y, Etemadan Z, Papi A. Detecting high-potential conditions of asphaltene precipitation in oil reservoir. Journal of Dispersion Science and Technology. 2018 Jul 3;39(7):943-51.
[17] Mohammadi S, Rashidi F, Mousavi‐Dehghani SA, Ghazanfari MH. On the effect of temperature on precipitation and aggregation of asphaltenes in light live oils. The Canadian Journal of Chemical Engineering. 2016 Sep;94(9):1820-9.
[18] Mahmoudi B, Zare-Reisabadi MR. Experimental study of temperature effect on onset pressure of asphaltene in live oil. Petroleum & Coal. 2015 Oct 1;57(4).
[19] Ashoori S, Balavi A. An investigation of asphaltene precipitation during natural production and the --CO2 injection process. Petroleum science and technology. 2014 Jun 3;32(11):1283-90.
[20] IP 143/84. Standard Methods for Analysis and Testing of Petroleum and Related Products.
[21] Abouie A, Darabi H, Sepehrnoori K. Data-driven comparison between solid model and PC-SAFT for modeling asphaltene precipitation. Journal of Natural Gas Science and Engineering. 2017 Sep 1;45:325-37.
[22] Hajizadeh N, Moradi G, Ashoori S. Modified SRK Equation of State for Modeling Asphaltene Precipitation. International Journal of Chemical Reactor Engineering. 2020 Feb 28;18(3).
[23] Zanganeh P, Dashti H, Ayatollahi S. Visual investigation and modeling of asphaltene precipitation and deposition during CO2 miscible injection into oil reservoirs. Fuel. 2015 Nov 15;160:132-9.
[24] Nghiem LX, Coombe DA, Ali SM. Compositional simulation of asphaltene deposition and plugging. InSPE Annual Technical Conference and Exhibition 1998 Jan 1. Society of Petroleum Engineers.
[25] Behbahani TJ, Ghotbi C, Taghikhani V, Shahrabadi A. Experimental investigation and thermodynamic modeling of asphaltene precipitation. Scientia Iranica. 2011 Dec 1;18(6):1384-90.
[26] Arya A, Liang X, Von Solms N, Kontogeorgis GM. Modeling of asphaltene onset precipitation conditions with cubic plus association (CPA) and perturbed chain statistical associating fluid theory (PC-SAFT) equations of state. Energy & Fuels. 2016 Aug 18;30(8):6835-52.